Polypropylene granule (which is often known as textile PP and chemical PP) is a special structure of polypropylene polymer that is used in the form of pellets (granules) to produce various products in various forms. Polypropylene granules are used to produce cable and wire coating, bottles, cans, etc. In the following, we will explain the technical specifications, features and applications of this granule.
What is polypropylene (pp)?
After polyethylene, polypropylene is the second most widely used thermoplastic in various industries, which recently in granulated form can have more applications in the production of products. Polypropylene, along with polyethylene, is made by the cracking process of naphtha (crude oil light distillation) under relatively mild temperature and pressure conditions and in the presence of the famous Ziegler-Natta catalyst. Compared to PE, PP has lower impact resistance, but higher usage temperature and higher tensile strength.
Classification of polypropylene
Polypropylene materials are divided into two general categories. Homopolymer polypropylene, which is produced from the polymerization of propylene monomer alone, and polypropylene copolymer, which is produced from the polymerization of propylene along with ethylene comonomer.
In common terminology, polypropylene homopolymer is called textile PP and polypropylene copolymer is called chemical PP.
Homopolymer
This polypropylene is produced from the polymerization of propylene monomer alone. In terms of physical and mechanical properties, the difference between polypropylene homopolymer (textile PP) and copolymer (chemical PP) is in their impact resistance, tensile strength and hardness. Although polypropylene homopolymer has higher tensile strength and hardness than polypropylene copolymer, its main weakness is its impact resistance. In fact, polypropylene homopolymer is more fragile than polypropylene copolymer. This weakness shows itself more in low temperatures, especially below zero degrees.
For this reason, the use of polypropylene homopolymer in the production of injection parts that are exposed to impact and low temperature is extremely limited. To fix this defect, ethylene monomer is injected into propylene during the polymerization process.
Copolymer
Polypropylene copolymer is produced from the polymerization of propylene along with ethylene comonomer. Polypropylene copolymer has a higher impact resistance than polypropylene homopolymer. By adjusting the amount of ethylene added to the polymer structure, adjusting the morphology of the copolymer, adjusting the type of crystallization, and also adjusting the molecular weight, the impact resistance can be controlled and raised to a good extent. Of course, it should be noted that increasing the impact resistance of polypropylene will reduce the hardness and stiffness of the polymer.
Adding ethylene to the structure of polypropylene during the polymerization of propylene reduces the structural order of polypropylene. Decreasing the structural order, in turn, causes a decrease in the amount of crystallization (crystallization) of polypropylene. Polypropylene copolymer itself is also divided into block and random copolymers, and the description of these two forms of copolymers is beyond the scope of this article.
Polypropylene granules
Polypropylene granule is a type of granular polymer that needs to be melted and then shaped in order to use it in various industries. In fact, all polymers can be converted into granules, depending on the type of application and the amount of viscosity, as well as the way they are polymerized. Due to the many advantages of granules, the granular form of polypropylene has a wider application for the production of composite products. Generally, most polymers for industrial use are first granulated and then melted to form the final product and then formed into the final product.
Characteristics of polypropylene granules
The most common use of polypropylene granules
Types of polypropylene granules based on usage
We examined the classification of granules based on their structure. Another type of classification for PP granules is based on uses and applications. Polypropylene granules are classified into six groups based on their uses:
Injection polypropylene granule (Injectoin Molding)
Fibers
Blow Molding Polypropylene Granule
Sheet/Film
pipe
Advantages of polypropylene granules
- Relatively cheap price of propylene monomer compared to monomers of other polymers
- The low price of PP compared to other polymers
- PP specific weight and light
- Flexibility and a wide range of PP production with variable physical and chemical properties
- Increasing new applications and improving the properties of new production grades
- Increasing the use of PP in medical devices and equipment and developing specific grade PP applications
- Increasing the use of PP as an alloy with other polymers
- Replacing polymers such as PS, PE, etc. with PP
Disadvantages
- Polypropylene has a high coefficient of thermal expansion, which limits temperature applications
- Sensitivity and damage to ultraviolet radiation
- Polypropylene has less resistance to chlorine and aromatic solvents
- Polypropylene is known to be difficult to paint because of its poor bonding properties.
- Polypropylene is highly flammable.
- Tendency to oxidize in open air
Buy polypropylene granules
Petrochemicals such as Shazand, Maron, Polynar, Rizal, Jam, Navid Zar Shimi and Bandaramam are producers of polypropylene granules.
Shams Javed company is one of the producers of this granule in Iran, which produces and supplies polypropylene granule using first grade petrochemical powder. Producers can call 02179615000 to buy polypropylene granules or refer to pp price page to know the weekly PP price.